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The ME export bus (added by Applied Energistics) is the opposite of the ME import bus, and allows you to take items from the ME network and put them into external sources such as chests and furnaces. Attach the export bus to any block containing items and feed it into the network via ME cable...
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Set it to extract only Yellorium and you are good to go, make sure to have lots of storage on the other side if you have a lot of Yellorium in your system. maybe use a Compacting Drawer, or a regular 1 slot Drawer with some upgrades to ensure there is space for all your Yellorium