I've been toying with that idea recently, actually. I've been testing the limits of the Fluid Transposer, and in one of the setups I used two Lava Fabricators and the single Fluid Transposer to run eight BR Turbines. All previous tests had worked off the premise of keeping all the Boilers stocked with a full stock (4 buckets) at all times. As my testing moved forward, I realized that I could squeeze an extra few Turbines out of the Fabricators by keeping a smaller stock in each Boiler.
If we move this forward further, as you suggested, we could time delivery of a single bucket per Boiler to hover just over 100°. Since this would be a massive leap forward in fuel efficiency, it would allow the expansion of previous systems in a big way (seeing as we currently have 4 buckets per Boiler, one might propose quadrupling our output).
The issue I am struck with is one of ensured timing. My first instinct is to simply push the system till it breaks, then dial backwards till I have the timing I'm looking for. If I were a coder, I would try to tie ComputerCraft into the whole thing to monitor Turbine speeds, Boiler temperatures, and any extra info I could think might be useful, but alas, I have the programming history of a third grade class gerbil. If I was running a small scale version of this, I would consider using timers (or simple redstone clocks) to dictate the flow to a Boiler, but when dealing with a larger system (16+ Boilers) it gets messy very quickly. I haven't ever used Steve's Factory Manager, although I understand the power that can be attained through it, so I may consider seeing what it presents for options at some point (I'm not sure SFM is in DW20, but it was in Infinity where this testing began).
Currently, my systems have run off a TD Resonant Servo (whitelisted to Lava Buckets)/set to round Robin mode. This has helped to assure the next bucket out goes to the Boiler most in need, but I hesitate to rely on it in a system that would run fuel and temperature so close to a fail point.
In your Coal Coke fed system, how many Boilers are you running? What are you using to time delivery? Any advice for scaling it to absurdity?