What Itharian said. The 36HP boilers are more space efficient, while the LP boilers take less fuel to heat. My personaly preference would of course be te more space efficient HP boilers. As for Omicron saying 60 hours for 97% efficiency, I have no idea where he pulled that number from. Maybe he's counting the heat up cost and how long you'd have to have it running to overcome that cost, but I know that for a 36hp boiler it should only be maybe 2-3 hours to heat it up to max temp, where its fuel efficiency is around 45% higher than other methods, as was mentioned earlier by someone else.
Also, while you would need something like 600 buckets of biofuel to heat up a 36HP boiler, you only need around 100-200 buckets of it already made - as long as your boiler powers your bifouel production process once it starts producing steam it can keep itself warm even without having so much biofuel, but having that many buckets ready beforehand makes it heat up faster than not having that windfall.
Another thing Itharian mentioned was Fuel, and I'll agree with him that it's very effective at heating up a boiler. In my post
here I show how you can setup the new liquid tesseracts to act as a fuel switch for boilers as well as how you have to hook them up to railcraft tanks. This works by having different liquids assigned to different frequencies and then when you want to swap fuel types you just change the frequency on the boiler's tesseract. This works very smoothly as well so you shouldn't have any problems swapping from one fuel type to another.
Edit: Something else to note, I hope the tesseracts get some form of extraction mode like the liquiducts so I can connect it directly to an iron tank valve instead of having to have a 2 long liquiduct pipe between them, but until that happens (if it happens) I'll sadly have to use that design.